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4.18.2019 Scott Wilson Speaks before FWC

4/18/2019

1 Comment

 
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1 Comment

Florida Lake George and St. Johns River in April ??

4/18/2019

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ARE "Herbicides" absolutely killing our lakes, fisheries, and ecosystems?

4/7/2019

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This is the Growth Pre Filtering Runoff

4/6/2019

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https://www.facebook.com/sunshineserpents
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#FWC Diquat Herbicide Spraying NOTICE: Locholoosa Lake Orange Lake

3/25/2019

0 Comments

 
Attention Orange Lake Guys:

According to FWC website, beginning 1.25.2019 they will be spraying DIQUAT on, ORANGE, LOCHOLOOSA all week.

Orange finally starting to show some improvement, healthy hydrilla in a few areas, and now this.

#MyFWC, you guys and your "Science" is BULLSHIT !!!

Using the #FWC "Waterbody Search Tool", the public can view the current workplan and schedule of operations for a particular waterbody.
  • Click the "Waterbody Name"
  • Click "OPEN" for the Current Aquatic Plant Control Workplan to view or print.
 
  • Weekly Schedule of Operation
  • Current Aquatic Plant Control Workplan

The Current Aquatic Plant Control Workplan will specify the following:
  • Contractor Area
  • Water Body
  • County
  • Major Water Uses
  • Water Body Code
  • Water Body Acres
  • Species of Concern
  • Management Objectives
  • Plants to be Controlled 
  • Acres to be Controlled
  • Estimated Cost
  • Control Methods
  • Public Notification Procedures
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Begin a Search for Herbicide Spraying click here
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Where is Spraying Allowed in Florida? Full List click here
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Using the #FWC "Waterbody Search Tool"​ search results for Lochloosa Lake and Orange Lake as follows:
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Slideshare program: Screen captured select comments left on Scott's Facebook blog post.
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TRADE OR OTHER NAMES
  • Aquacide
  • Dextrone
  • Reglone
  • Reglox
  • Weedtrine-D
  • Aquakill
  • Vegetrole
  • Deiquat
  • Reglon
  • Tag

REGULATORY STATUS
  • moderately toxic

INTRODUCTION
  • causing injury only to the parts of the plant to which it is applied
  • it does not spare 'nontarget' plants from its herbicidal effects
  • causes a leaf or an entire plant to dry out quickly

ACUTE TOXICITY
  • moderately toxic
  • fatal to humans if swallowed, inhaled, or absorbed through the skin
  • ​Concentrated solutions may cause severe irritation of the mouth, throat, esophagus and stomach followed by nausea, vomiting, diarrhea, severe drying out of bodily tissues, gastrointestinal discomfort, chest pain, diarrhea, kidney failure, and toxic liver damage
  • Very large doses of the herbicide can result in convulsions and tremors
  • Rats given lethal doses of diquat showed few signs of illness during the first 24 hours. They then exhibited lethargy, pupil dilation, respiratory distress, weight loss weakness and finally death over the course of 2 to 14 days after dosing. Similar patterns of symptoms occurred in mice, guinea pigs, rabbits, dogs, cows and hens
  • acutely toxic when it is absorbed through the skin and the possibility for poisoning increases with repeated exposure
  • demonstrated toxicity of this compound is sufficient to raise serious human health concerns. Small amounts of diquat can cause skin irritation and sores, as well as delayed healing of cuts and wounds. When absorbed through the skin, some commercial concentrate formulations of diquat can cause symptoms similar to those that occur when it is eaten
  • There have been reports of workers who have had softening and color changes in one or more fingernails after contact with concentrated diquat dibromide solutions. In some instances, the nail was shed, and did not grow in again
  • Repeated dermal doses cause mild redness, thickening, and scabbing
  • Diquat dibromide also causes eye irritation
  • Several cases of severe injury to human eyes have been reported after accidental splashings. In each case, initial irritation was mild, but after several days, serious burns and sometimes scarring of the cornea developed
  • Direct or excessive inhalation of diquat dibromide spray mist or dust may result in oral or nasal irritation, nosebleeds, headache, sore throat, coughing, and symptoms similar to those from ingestion of diquat

CHRONIC TOXICITY
  • Cataract formation is the most significant effect of chronic exposure to diquat
  • repeated, or prolonged, dermal contact with diquat dibromide range from inflammation of the skin, to general bodily ('systemic') poisoning, as evidenced by injury to internal organs, primarily the kidneys.
  • Chronic exposure may damage skin, which allows more absorption of the herbicide
  • Repeated applications of 42 mg/kg of diquat killed four out of six rabbits tested
  • Repeated inhalation exposure of rats to 1.9 mg/m3 caused inflammatory changes in connective tissues, damage to the kidneys and heart, abnormal levels of several liver enzymes, low white blood cell counts, high red blood cell counts, and depressed cholinesterase activity

Reproductive Effects
  • Fertility was reduced in male mice given diquat dibromide during different stages of sperm formation

Teratogenic Effects
  • diquat dibromide is thought by other researchers to have the potential to cause birth defects

Organ Toxicity
  • diquat is most harmful to the gastrointestinal tract (GIT), kidneys, and liver
  • Severe congestion and ulceration of the stomach and bowel are produced by the herbicide
  • large doses of diquat are given, there is evidence of stretching and irritation of the GIT and thickening of the walls of the alveoli, or air cells of the lungs
  • Acute death occurs in the cells of the small glandular tubes that process urine in the kidney
  • Cataracts are caused when smaller amounts of diquat are given
  • water is apparently removed from other tissues as well
  • Dehydration can result
  • amount of water which is removed depends on how much diquat dibromide is given
  • Poisoning by diquat may affect the liver and kidneys

Fate in Humans and Animals
  • Diquat dibromide may be absorbed by humans following oral ingestion, dermal exposure or inhalation of spray mists
  • Oral doses of diquat are metabolized mainly within the intestines rather than in the body proper, with metabolites being excreted in the feces
  • cattle an oral dose was recovered in the milk

Effects on Birds
  • moderately toxic to practically nontoxic to birds
  • Signs of poisoning... included instability, wing-drop and lack of movement

Effects on Aquatic Organisms
  • ​Diquat dibromide is slightly toxic to fish
  • lethal concentration fifty, or LC50 is that concentration of a chemical in air or water that kills half of the experimental subjects exposed
  • Some species of fish may be harmed
  • Oxygen can become depleted in diquat-treated water by decaying aquatic plants. This decreases the amount of oxygen available for fish survival.
  • yellow perch suffer significant respiratory stress
  • Strip application of the herbicide over water is recommended to prevent large scale fish kills
  • One investigation into the persistence of diquat in fish showed that one half of the herbicide was lost in less than three weeks

Effects on Other Animals (Nontarget species)
Cows are particularly sensitive to the toxic effects of this material

Breakdown of Chemical in Soil and Groundwater
  • diquat dibromide comes in contact with soil, it becomes strongly adsorbed to clay particles or organic matter in the soil for long periods of time
  • strong chemical bonds formed by diquat adsorption to soil particles make the herbicide biologically and chemically inactive.
    • ​carried away, or leached, by water seeping through the soil
  • Traces, or residues, of diquat have been found to persist in soil for many years with very little degradation
  • Soil capacity for adsorption of diquat is so high...
  • there is also evidence that diquat has the ability to eventually use up, or saturate, all the available adsorption sites on soil clay particles
  • Groundwater quality can be affected if soil adsorption sites become totally saturated because water moving down through the soil can carry any non adsorbed herbicide into the groundwater
  • Studies on the erosion of diquat-treated soils near bodies of water indicate that diquat stays bonded to soil particles, remaining biologically inactive in surface waters, such as lakes, rivers and ponds

Breakdown of Chemical in Water
  • diquat is applied to open water, it disappears rapidly because it binds to suspended particles in the water. These particles are then taken up by plants
  • Twenty-two days after a weed infested artificial lake was treated, only 1% of the applied diquat remained in the water and 19% was adsorbed to sediments.
  • Diquat has been found in the bottom soil of pools and ponds four years after application
  • Diquat will photodegrade in surface layers of water in 1 to 3 or more weeks when it is not adsorbed to suspended particles
  • The EPA requires a 14-day interval between treatment of water with diquat dibromide and use of treated waters for domestic, livestock, or irrigation purposes. Swimming, fishing and watering of domestic animals should not be allowed for at least 14 days after application of the herbicide to water. The herbicide cannot be used for any purpose in commercial fish processing areas

Breakdown of Chemical in Vegetation
  • intermediate residues of diquat are incorporated with the plant materials into the soil, where, through a process called 'microbial degradation, they are changed into carbon dioxide by soil microorganisms
  • Diquat dibromide is also rapidly absorbed by weeds in water, which causes the concentrations of the material in plant tissue to be higher than in surrounding water.
  • Low concentrations of the herbicide in water are adequate for controlling aquatic weeds
  • diquat dibromide is a nonselective herbicide with non-crop use patterns that overlap endangered plant habitats, it may present a danger to nontarget plants, including endangered species​

PHYSICAL PROPERTIES AND GUIDELINES
  • contains small amounts of a highly toxic chemical impurity, ethylene dibromide (EDB)
  • When heated to decomposition, very toxic fumes are emitted from diquat
  • pose a slight fire hazard if exposed to heat or flame
  • poses a fire and explosion hazard in the presence of strong oxidizers
  • Thermal decomposition of diquat will release toxic oxides of nitrogen and carbon and toxic and corrosive fumes of bromides
  • Diquat is corrosive
  • Commercial use formulations of diquat contain corrosion inhibitors, ingredients that slow down or prevent corrosion
  • corrosion inhibitors, concentrated formulations will corrode metals, especially aluminum, and should be stored only in the original container
  • diquat dibromide is incompatible with anionic wetting agents such as alkyl sulfamates
  • protective clothing should be worn when handling the concentrated product
  • Skin and eye contact with diquat, especially from drift, should be avoided
  • Breathing diquat spray (mist) should also be avoided
  • Respiratory equipment is recommended, especially in situations in which exposure to drifting spray is possible
  • 24-hour reentry interval is set by EPA for crop sites, golf courses, and rights-of-way that are treated with diquat dibromide
  • 14-day period is also required by EPA between diquat treatment of water bodies and use of treated water for domestic, swimming, irrigation, and/or livestock feeding purposes
  • Diquat dibromide may not be used where commercial fish processing is practiced

Extoxnet DIQUAT
0 Comments

Orange Lake Fish Catch with Tumors and Un-Natural Sores

3/24/2019

0 Comments

 
Solid 7, on Bryan Heaberlin spook on Orange Lake.

Note large petruding tumor and large number of tumors on the other side of fish.

This makes the second large Orange Lake fish with totally unnatural sores.

Herbicide spraying connection??
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This is a slideshare of screen captures.  Credit linked to screen capture.

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What spraying is going on in your area?  click here
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TRADE OR OTHER NAMES
  • Aquacide
  • Dextrone
  • Reglone
  • Reglox
  • Weedtrine-D
  • Aquakill
  • Vegetrole
  • Deiquat
  • Reglon
  • Tag

REGULATORY STATUS
  • moderately toxic

INTRODUCTION
  • causing injury only to the parts of the plant to which it is applied
  • it does not spare 'nontarget' plants from its herbicidal effects
  • causes a leaf or an entire plant to dry out quickly

ACUTE TOXICITY
  • moderately toxic
  • fatal to humans if swallowed, inhaled, or absorbed through the skin
  • ​Concentrated solutions may cause severe irritation of the mouth, throat, esophagus and stomach followed by nausea, vomiting, diarrhea, severe drying out of bodily tissues, gastrointestinal discomfort, chest pain, diarrhea, kidney failure, and toxic liver damage
  • Very large doses of the herbicide can result in convulsions and tremors
  • Rats given lethal doses of diquat showed few signs of illness during the first 24 hours. They then exhibited lethargy, pupil dilation, respiratory distress, weight loss weakness and finally death over the course of 2 to 14 days after dosing. Similar patterns of symptoms occurred in mice, guinea pigs, rabbits, dogs, cows and hens
  • acutely toxic when it is absorbed through the skin and the possibility for poisoning increases with repeated exposure
  • demonstrated toxicity of this compound is sufficient to raise serious human health concerns. Small amounts of diquat can cause skin irritation and sores, as well as delayed healing of cuts and wounds. When absorbed through the skin, some commercial concentrate formulations of diquat can cause symptoms similar to those that occur when it is eaten
  • There have been reports of workers who have had softening and color changes in one or more fingernails after contact with concentrated diquat dibromide solutions. In some instances, the nail was shed, and did not grow in again
  • Repeated dermal doses cause mild redness, thickening, and scabbing
  • Diquat dibromide also causes eye irritation
  • Several cases of severe injury to human eyes have been reported after accidental splashings. In each case, initial irritation was mild, but after several days, serious burns and sometimes scarring of the cornea developed
  • Direct or excessive inhalation of diquat dibromide spray mist or dust may result in oral or nasal irritation, nosebleeds, headache, sore throat, coughing, and symptoms similar to those from ingestion of diquat

CHRONIC TOXICITY
  • Cataract formation is the most significant effect of chronic exposure to diquat
  • repeated, or prolonged, dermal contact with diquat dibromide range from inflammation of the skin, to general bodily ('systemic') poisoning, as evidenced by injury to internal organs, primarily the kidneys.
  • Chronic exposure may damage skin, which allows more absorption of the herbicide
  • Repeated applications of 42 mg/kg of diquat killed four out of six rabbits tested
  • Repeated inhalation exposure of rats to 1.9 mg/m3 caused inflammatory changes in connective tissues, damage to the kidneys and heart, abnormal levels of several liver enzymes, low white blood cell counts, high red blood cell counts, and depressed cholinesterase activity

Reproductive Effects
  • Fertility was reduced in male mice given diquat dibromide during different stages of sperm formation

Teratogenic Effects
  • diquat dibromide is thought by other researchers to have the potential to cause birth defects

Organ Toxicity
  • diquat is most harmful to the gastrointestinal tract (GIT), kidneys, and liver
  • Severe congestion and ulceration of the stomach and bowel are produced by the herbicide
  • large doses of diquat are given, there is evidence of stretching and irritation of the GIT and thickening of the walls of the alveoli, or air cells of the lungs
  • Acute death occurs in the cells of the small glandular tubes that process urine in the kidney
  • Cataracts are caused when smaller amounts of diquat are given
  • water is apparently removed from other tissues as well
  • Dehydration can result
  • amount of water which is removed depends on how much diquat dibromide is given
  • Poisoning by diquat may affect the liver and kidneys

Fate in Humans and Animals
  • Diquat dibromide may be absorbed by humans following oral ingestion, dermal exposure or inhalation of spray mists
  • Oral doses of diquat are metabolized mainly within the intestines rather than in the body proper, with metabolites being excreted in the feces
  • cattle an oral dose was recovered in the milk

Effects on Birds
  • moderately toxic to practically nontoxic to birds
  • Signs of poisoning... included instability, wing-drop and lack of movement

Effects on Aquatic Organisms
  • ​Diquat dibromide is slightly toxic to fish
  • lethal concentration fifty, or LC50 is that concentration of a chemical in air or water that kills half of the experimental subjects exposed
  • Some species of fish may be harmed
  • Oxygen can become depleted in diquat-treated water by decaying aquatic plants. This decreases the amount of oxygen available for fish survival.
  • yellow perch suffer significant respiratory stress
  • Strip application of the herbicide over water is recommended to prevent large scale fish kills
  • One investigation into the persistence of diquat in fish showed that one half of the herbicide was lost in less than three weeks

Effects on Other Animals (Nontarget species)
Cows are particularly sensitive to the toxic effects of this material

Breakdown of Chemical in Soil and Groundwater
  • diquat dibromide comes in contact with soil, it becomes strongly adsorbed to clay particles or organic matter in the soil for long periods of time
  • strong chemical bonds formed by diquat adsorption to soil particles make the herbicide biologically and chemically inactive.
    • ​carried away, or leached, by water seeping through the soil
  • Traces, or residues, of diquat have been found to persist in soil for many years with very little degradation
  • Soil capacity for adsorption of diquat is so high...
  • there is also evidence that diquat has the ability to eventually use up, or saturate, all the available adsorption sites on soil clay particles
  • Groundwater quality can be affected if soil adsorption sites become totally saturated because water moving down through the soil can carry any non adsorbed herbicide into the groundwater
  • Studies on the erosion of diquat-treated soils near bodies of water indicate that diquat stays bonded to soil particles, remaining biologically inactive in surface waters, such as lakes, rivers and ponds

Breakdown of Chemical in Water
  • diquat is applied to open water, it disappears rapidly because it binds to suspended particles in the water. These particles are then taken up by plants
  • Twenty-two days after a weed infested artificial lake was treated, only 1% of the applied diquat remained in the water and 19% was adsorbed to sediments.
  • Diquat has been found in the bottom soil of pools and ponds four years after application
  • Diquat will photodegrade in surface layers of water in 1 to 3 or more weeks when it is not adsorbed to suspended particles
  • The EPA requires a 14-day interval between treatment of water with diquat dibromide and use of treated waters for domestic, livestock, or irrigation purposes. Swimming, fishing and watering of domestic animals should not be allowed for at least 14 days after application of the herbicide to water. The herbicide cannot be used for any purpose in commercial fish processing areas

Breakdown of Chemical in Vegetation
  • intermediate residues of diquat are incorporated with the plant materials into the soil, where, through a process called 'microbial degradation, they are changed into carbon dioxide by soil microorganisms
  • Diquat dibromide is also rapidly absorbed by weeds in water, which causes the concentrations of the material in plant tissue to be higher than in surrounding water.
  • Low concentrations of the herbicide in water are adequate for controlling aquatic weeds
  • diquat dibromide is a nonselective herbicide with non-crop use patterns that overlap endangered plant habitats, it may present a danger to nontarget plants, including endangered species​

PHYSICAL PROPERTIES AND GUIDELINES
  • contains small amounts of a highly toxic chemical impurity, ethylene dibromide (EDB)
  • When heated to decomposition, very toxic fumes are emitted from diquat
  • pose a slight fire hazard if exposed to heat or flame
  • poses a fire and explosion hazard in the presence of strong oxidizers
  • Thermal decomposition of diquat will release toxic oxides of nitrogen and carbon and toxic and corrosive fumes of bromides
  • Diquat is corrosive
  • Commercial use formulations of diquat contain corrosion inhibitors, ingredients that slow down or prevent corrosion
  • corrosion inhibitors, concentrated formulations will corrode metals, especially aluminum, and should be stored only in the original container
  • diquat dibromide is incompatible with anionic wetting agents such as alkyl sulfamates
  • protective clothing should be worn when handling the concentrated product
  • Skin and eye contact with diquat, especially from drift, should be avoided
  • Breathing diquat spray (mist) should also be avoided
  • Respiratory equipment is recommended, especially in situations in which exposure to drifting spray is possible
  • 24-hour reentry interval is set by EPA for crop sites, golf courses, and rights-of-way that are treated with diquat dibromide
  • 14-day period is also required by EPA between diquat treatment of water bodies and use of treated water for domestic, swimming, irrigation, and/or livestock feeding purposes
  • Diquat dibromide may not be used where commercial fish processing is practiced

Extoxnet DIQUAT
0 Comments

Hydrilla has continually become immune to chemicals

2/27/2019

0 Comments

 
Video by Joanna MaGrath will cover via audio Scott Wilson's
​blog post, break it down and add information of education.
Did you know i-Cide means i-Kill?
?!? Time to END the Killing ?!?
Hydrilla has continually become immune to chemicals by Scott Wilson
Continued: Aquatic Spraying Co Research click here
Thru 40 years of chemical spraying to attempt irradication of Hydrilla , Hydrilla has continually become immune to chemicals used requiring a huge step up in active doses of "Sonar" used until the early 2000's. It became immune to even higher doses so IFAS, FWC,FAMPS switched to "Endothol". Now stronger doses of this chemical used in conjunction with "Diquat" are not doing the trick. So the State now has approved this chemical "ProcellaCOR" to treat hydrilla. Look at testing about ten pages in, this garbage although they say: water is drinkable day of treatment, this stuff TOTALY EVAPORATES hydrilla in 24 hours, but safe for the environment?? I think every FWC director, IFAS scientists, DEP supervisor,and every FAPMS board member should be made to enjoy a tall cool glass of water at recommended dilutions to be sprayed across Florida RANT OVER
​Sonar (Google Search)
  • SePRO Material Safety Data Sheet click here
  • Environmental precautions: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). May be harmful to the environment if accidentally released in large quantities. Collect spillage.
    • Sonar® A.S. Aquatic Herbicide
    • ​Aquatic herbicide
    • EPA Registration No. 67690-4
    • This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).
    • EYE IRRITATION - Category 2B - H320 - Causes eye irritation.
    • AQUATIC HAZARD (ACUTE) - Category 2
    • AQUATIC HAZARD (LONG-TERM) - Category 2
    • H411 - Toxic to aquatic life with long lasting effects.
    • P273 - Avoid accidental release to the environment.
    • P261 - Avoid breathing vapor.
    • UN proper shipping name: 
      • ​DOT Classification: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Fluridone)
      • IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Fluridone). Marine pollutant (Fluridone)
      • IATA: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Fluridone)
    • Environmental Hazards: Yes
    • Immediate (acute) health hazard: Yes
    • Notice to reader
      To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein.
      Final determination of suitability of any material is the sole responsibility of the user.
      All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
Endothol (FWC: Endothall acid) (Endothall)
  • Endothall is the common name of the active ingredient endothal acid (7-oxabicyclo[2,2,1] heptane-2,3-dicarboxylic acid). Endothall products are used to control a wide range of terrestrial and aquatic plants. Continue reading click here
  • Pub Chem Endothall (Continue reading click here)
    • GHS Hazard Statements
      • ​H300 (88.46%): Fatal if swallowed [Danger Acute toxicity, oral]
      • H301 (11.54%): Toxic if swallowed [Danger Acute toxicity, oral]
      • H312 (100%): Harmful in contact with skin [Warning Acute toxicity, dermal]
      • H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]
      • H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]
      • H335 (100%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]
      • H400 (88.46%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]
  • Caymen Chemical MSDS (Continue reading click here)
    • Endothall
    • Product Code: 17404
    • Synonyoms: 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic acid; Aquathol; Endothal Acid; Hydrothol; NSC 112771;
    • Acute Toxicity: Oral, Category 3
    • Acute Toxicity: Skin, Category 4
    • Skin Corrosion/Irritation, Category 2
    • Serious Eye Damage/Eye Irritation, Category 2
    • Specific Target Organ Toxicity (single exposure), Category 3
    • H301: Toxic if swallowed.
    • H312: Harmful in contact with skin.
    • H315: Causes skin irritation.
    • H319: Causes serious eye irritation.
    • H335: May cause respiratory irritation.
    • P261: Avoid breathing {dust/fume/gas/mist/vapors/spray}.
    • P302+352: IF ON SKIN: Wash with plenty of soap and water.
    • P332+313: If skin irritation occurs, get medical advice/attention.
    • P337+313: If eye irritation persists, get medical advice/attention.
    • Adverse Human Health Effects and Symptoms:
      • Causes serious eye irritation.
      • Causes skin irritation.
      • Harmful in contact with skin.
      • Material may be irritating to the mucous membranes and upper respiratory tract. May be harmful by inhalation or skin absorption.
      • May cause respiratory system irritation.
      • Toxic if swallowed.
      • To the best of our knowledge, the toxicological properties have not been thoroughly investigated.
    • GHS Classification
      • Acute Tox.(O) 3: H301
      • Acute Tox.(D) 4: H312
      • Skin Corr. 2: H315
      • Eye Damage 2: H319
      • STOT (SE) 3: H335 H336
    • Accidental Release Measures
      • Environmental: ​Take steps to avoid release into the environment, if safe to do so.
    • Exposure Controls/Personal Protection: Use process enclosures, local exhaust ventilation, or other engineering controls to control airborne
    • Ecological Information
      • ​Avoid release into the environment.
      • Runoff from fire control or dilution water may cause pollution.
    • DISCLAIMER: This information is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes.
Diquat (Alligare Diquat Herbicide) (SDS)
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Alligare Diquat Herbicide
  • EPA Reg. No.: 81927-35
  • ​​Common Name: Diquat dibromide
  • Chemical Name: [6,7-dihydrodipyrido(1,2-a:2’,1’-c) pyrazinediium dibromide]
  • Toxic if inhaled (H331)
  • Harmful if swallowed (H302)
  • May be corrosive to metals (H290)
  • Very toxic to aquatic life with long lasting effects â€‹(H400+H410)
  • Acute Toxicity, Inhalation Category 3
  • Acute Toxicity, Oral Category 4
  • Hazardous to the Aquatic Environment, Acute Category 1
  • ​Hazardous to the Aquatic Environment, Chronic Category 1
  • Avoid breathing mist/vapors/spray
  • Storage: Do not contaminate feed, foodstuffs, or drinking water.
  • ECOLOGICAL INFORMATION
    • ​This product is toxic to aquatic invertebrates.
    • AQUATIC TOXICITY
      • ​Rainbow Trout (96-hr LC50): 14.83 ppm
      • Daphnia (48-hr EC50): 0.77 ppm
      • Green Algae (EC50): 9.4 ppb
      • Chronic estuarine/marine invertebrates (NOAEC): 0.052 mg/L
      • Duckweed (NOAEC): 0.0012 mg/L
    • AVIAN TOXICITY
      • Mallard Duck (8-day Dietary LC50): 60.6 mg/kg
  • REGULATORY INFORMATION
    • ​HAZARDS TO HUMANS AND DOMESTIC ANIMALS
    • CAUTION. Harmful if inhaled. Harmful if swallowed. Causes moderate eye irritation. Avoid breathing spray mist. Avoid contact with eyes or clothing.
    • ENVIRONMENTAL HAZARDS - This product is toxic to aquatic invertebrates.
    • For Terrestrial Uses, do not apply directly to water, or to areas where surface water is present, or to intertidal areas below the mean high water mark. Do not contaminate water when disposing of equipment wash water.
    • For Aquatic Uses, do not apply directly to water except as specified on this label.
    • All pesticides are governed under the Federal Insecticide, Fungicide, and Rodenticide Act (FIFRA).
  • Other Information: THIS INFORMATION IN THIS SDS IS BASED ON DATA AVAILABLE AS OF THE REVISION DATE GIVEN HEREIN, AND BELIEVED TO BE CORRECT. CONTACT ALLIGARE, LLC TO CONFIRM IF YOU HAVE THE MOST CURRENT MSDS. JUDGMENTS AS TO THE SUITABILITY OF THE INFORMATIONHEREIN FOR THE INDIVIDUAL’S OWN USE OR PURPOSES IS NECESSARILY THE INDIVIDUAL’SOWN RESPONSIBILITY. ALTHOUGH REASONABLE CARE HAS BEEN TAKEN IN THE PREPARATION OF SUCH INFORMATION, ALLIGARE, LLC EXTENDS NO WARRANTIES, MAKES NO REPRESENTATIONS, AND ASSUMES NO RESPONSIBILITY AS TO THE ACCURACY OR SUITABILITYOF SUCH INFORMATION FOR APPLICATION TO THE INDIVIDUAL’S PURPOSES OR THECONSEQUENCES OF ITS USE.
ProcellaCOR
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Slideshare Presentation Florpyrauxifen-benzyl Herbicide
Source of information click here
Slideshare Presentation
PorcellaCOR - Review the presentations.  They make it appear to be so great! ...BUT, read what is it really about "TOXIC" !!!
​(Source of Info Click here)
Material Safety Data Sheets Slideshare Presentations on
  • ProcellaCOR EC
  • ProcellaCOR SC
ProcellaCOR EC SAFETY DATA SHEET "Slideshare Presentation"
https://www.sepro.com/Documents/ProcellaCOR_EC--SDS.pdf

ProcellaCOR SC SAFETY DATA SHEET "Slideshare Presentation"
https://www.sepro.com/Documents/ProcellaCOR_SC--SDS.pdf

This information is from the U.S. EPA
​Notice of Pesticide Registration
  • ProcellaCOR SC
  • ProcellaCOR EC
ProcellaCOR SC
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ProcellaCOR EC
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Slideshare Presentation
Documents Submitted to the U.S. EPA

ProcellaCOR EC is for "Both"
​Rice and Aquatic
Labels: - Rice and Aquatic

Both Read: Same "Active Ingredients" and "Other Ingredients"

Both Read: Hazards to Humans and Domestic Animals

Rice: Do NOT Apply Directly to water and Do NOT fish or commercially grow fish, shellfish or crustaceans on treated acres during the year of treatment
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ProcellaCOR "Active Ingredient"
>>> ​Florpyrauxifen-benzyl <<<

Screen Captured from ProcellaCOR MSDS Document:
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Per the ProcellaCOR MSDS Document...
EPA Filing Name ProcellaCOR EC
Florpyrauxifen-benzyl

(Hazard to Humans and Domestic Animals)

Information from the PubChem Website (link)
From: PubChem Synonyms
florpyrauxifen-benzyl

(TOXIC to Aquatic Life with Long Lasting Effects.!!!)
PubChem PROOF: â€‹Screen Captures Below from website
Source Link
https://pubchem.ncbi.nlm.nih.gov/compound/70495450#section=Top
(Click Screen Captures to Enlarge)
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^^^^^^^^^^^^^
​"May Cause an Allergic Skin Reaction"
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^^^^^^^^^^^^^
"Very Toxic to Aquatic Life"
"Very Toxic to Aquatic Life with Long Lasting Effects"
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^^^^^^^^^^^^^
"Very Toxic to Aquatic Life
​with Long Lasting Effects"
(Porcellacor Aquatic Herbicide by SePRO​)
  • Slide Program click here
  • https://www.regulations.gov/docket?D=EPA- HQ-OPP-2016-0560
  • https://www.federalregister.gov/documents/2017/10/06/2017-21614/florpyrauxifen-benzyl-pesticide-tolerances
  • ProcellaCOR herbicide and sample testing FWC 18/19-09
  • PROCELLACOR HERBICIDE AND SAMPLE TESTING
  • Promising New Herbicide Technologies for hte Management of Old World Climbing Fern
  • About Aquatic Weeds
  • The Stewards of Water Blog
  • Dogs as sentinels: Blue-green algae brings toxic mystery to Minn. waters
  • Ten Rules of Engagement for Battling Aquatic Weeds
  • Poisonous Algae Blooms Threaten People, Ecosystems Across U.S.
  • Monitoring and Responding to Cyanobacteria and Cyanotoxins in Recreational Waters
  • Common aquatic weeds
Changes were made to their website... Why???
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^^^ What the website use to say ^^^
Now what is says
(Doesn't say on their website safe for people and pets anymore)
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Are you reading the information on ProcellaCOR?
IT IS TOXIC

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^^^ What is did say ^^^
What is says now
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SePRO Latest News
Where sources of information was found
  • U.S. ENVIRONMENTAL PROTECTION AGENCY PROCELLACOR EC by SePRO Corporation
  • Auxins: University of Florida IFAS - Citrus Production Guide: Plant Growth Regulators 
  • Florpyrauxifen-benzyl​: Pub Chemchem Benzyl 4-amino-3-chloro-6-(4-chloro-2-fluoro-3-methoxyphenyl)-5-fluoropyridine-2-carboxylate
  • Summary of Herbicide Mechanism of Action According to the Weed Science Society of America (WSSA)
  • HRAC Group O
  • Paspalidium geminatum (Common Name(s): Egyptian paspalidium)
  • Common Aquatic Plants of Lake Okeechobee: Identification, Value, and Management1
  • Plants of the Kissimmee-Okeechobee-Everglades Ecosystem
  • How to ID grass and fish it effectively
  • What is a temperature inversion?
Notes:
  • Background on the Aquatic Herbicides Registered for Use in Florida (Continue reading click here)
  • Herbicides Registered for Use in Florida Waters and Trade Names (Continue reading click here)
  • Aquatic Plants Licenses & Permits​ (Continue click here)
  • Invasive Plant Management Contacts (Continue click here)
  • Summary of Herbicide Mechanism of Action According to the Weed Science Society of America (WSSA) (Continue click here)
  • Herbicide Resistance: Chemical Control Considerations (Continue reading click here)
  • Developing Management Plans (Continue reading click here)
  • Aquatic Pest Control – SM 3 IFAS Extension Bookstore
  • Chemical Control (Continue reading click here)
  • EPA Registration Process: Aquatic Herbicide Testing, Toxicity, and EPA Registration
  • Pesticides​
  • Pesticide Reregistration Status
  • AES Bureau of Pesticides - Division of Agricultural Environmental Services
  • Ecological Risk Assessment
  • Background on the Aquatic Herbicides Registered for Use in Florida
  • ​Aquatic Herbicide Testing, Toxicity, and EPA Registration (Continue reading click here)
  • Sonar®The leading aquatic herbicide
What does the University of Florida IFAS Extension say about "Pesticides".............
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What Herbicides are approved to apply in Florida's water?
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This is a Yearly Report by FWC.  The information below I pulled from this report.............
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EPA ProcellaCOR SC
  • Read Registration
ProcellaCOR SC apply 2018 as reported by FWC 
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Slideshare Presentation (click the arrow to see each frame)
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Open as a .pdf
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Federal Register... The Importance of "Checking it".
(This is a Slideshare Presentation of Florpyrauxifen-Benyl)
Which EPA Agency Regulates Pesticides for Florida . . .
(The Importance of Researching the EPA Regarding
​Pesticide Registration, Label, Research, and Data)
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How to search a chemical through the EPA website:
Pesticide Chemical Search:
  • https://iaspub.epa.gov/apex/pesticides/f?p=chemicalsearch:1
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Search for 
  • Sonar
  • Endothol
  • Diquat
  • ProcellaCOR
produced results as follows:
Sonar
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Diquat
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Pesticide Product and Label System Search:
  • https://iaspub.epa.gov/apex/pesticides/f?p=PPLS:1
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Search for 
  • Sonar
  • Endothol
  • Diquat (Many)
  • ProcellaCOR EC
  • Procellacor SC
produced results as follows:
To Quote Rachael Carson, "same chemical different name"
Sonar
Chemical Name: Fluridone
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Fluridone a/k/a ... (or click here)
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Diquat
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0 Comments

FWC Meeting 2.21.2019

2/27/2019

0 Comments

 
by Mike Knepper 
​Source of Video click here
MORE Videos by Becky Williams: 2-21-19 FWC Meeting
0 Comments

Allen's Blog: The Culture of Managing Invasive Aquatic Plants Attacking the Consequence, Ignoring the Cause

1/16/2019

0 Comments

 
Source of Article click here
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Source of Article click here
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Continue reading this blog click here
FOLLOW THIS BLOG CLICK HERE
0 Comments

Short of fish

1/16/2019

0 Comments

 
Source of Article
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0 Comments
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    Disclaimer, I am no scientist, or biologist but have spent my entire 57 yrs as a successful fisherman, as a commercial/ charter captain in the keys for 24 years. I have also regularly fished every major freshwater lake ,and chain lake systems since 1967. And our family handed down our Kissimmee river weekend fish camp we have owned since the 1980's.

    The first thing any truly successful fisherman learns is to "read the water" ,its quality, movement, external conditions, and food supplies through the food chain. Although I admittedly am not science educated, I call BS on the science. It has been Florida' "best and brightest" since the late 50's that result in the monumental mess we have now.

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